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Please view attachment – 2 years ago **files (3)** – ## OSH4302UnitIII_JHAforAssignment.docx – ## UnitIII_SDSPaint.pdf – UnitIII_SDSSolvent.pdf **## OSH4302UnitIII_JHAforAssignment.docx** You have been tasked with identifying health hazards associated with a production line at a manufacturing fa…
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**files (3)**
– ## OSH4302UnitIII_JHAforAssignment.docx
– ## UnitIII_SDSPaint.pdf
– UnitIII_SDSSolvent.pdf
**## OSH4302UnitIII_JHAforAssignment.docx**
You have been tasked with identifying health hazards associated with a production line at a manufacturing facility.
Employees at the beginning of the line use a solvent to clean the surface of medium-size auto parts, and then they place the parts on a moving line. As the parts move along the line, an employee sprays them with a powder coating, and the parts move through an oven. Another employee removes the parts from the line and places them in slots in a cart for transporting to shipping.
You have been provided
[safety data sheets for the solvent](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404059_1/xid-148404059_1) used for cleaning the parts and the
[powder coating](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404058_1/xid-148404058_1) that is used. Use the
[Basic Job Hazard Analysis form](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404057_1/xid-148404057_1) to identify the potential health hazards associated with the process. You will use the Basic Job Hazard Analysis form to enter your responses and to answer the four questions listed below.
Prepare a two-page homework assignment at the bottom of the JHA form summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
**Unit III BASIC JOB HAZARD ANALYSIS FORM**
**Directions:** List the steps involved in performing the process, and identify the potential hazards associated with each step.
| | |
| — | — |
| **Steps to Perform the Work Process** | **Hazards/Potential Hazards** |
| 1. | |
| 2. | |
| 3. | |
| 4. | |
| 5. | |
| 6. | |
Prepare a two-page homework assignment summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
1. What are the health hazards associated with the operation?
2. What are the primary exposure routes associated with each health hazard?
3. Are there any potential acute or chronic health effects for any of the health hazards you identified?
4. Are there any special hazards associated with any of the health hazards?
You may use the safety data sheets provided above, information from the OSHA or NIOSH websites, or academic references from the Internet to answer the questions. Citations are not required for this homework assignment; however you may want to use them in order to answer the questions.
**## UnitIII_SDSPaint.pdf**
SAFETY DATA SHEET
Revision date 25-Apr-2015 Version 2
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Code ALS5N0035
Product Name EARTH VEIN
Other means of identification
No information available
Recommended use of the chemical and restrictions on use
Paint, Coatings
Details of the supplier of the safety data sheet
See section 16 for more
information
The Valspar Corporation
PO Box 1461
Minneapolis, MN 55440
E-mail address msds@valspar.com
Emergency telephone number
United States of America 1-888-345-5732
American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924
Section 2: HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Product Code ALS5N0035
HAZARD STATEMENTS
Page 1 / 8
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
AGHS – USA OSHA SDS
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No weight-%
Carbon black 1333-86-4 1 – 3
Titanium dioxide 13463-67-7 0.1 – 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General advice
Get medical advice/attention if you feel unwell.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
PREVENTION
Do not handle until all safety precautions have been read and understood.
RESPONSE
Get medical advice/attention if you feel unwell.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
STORAGE
Store in a closed container.
DISPOSAL
Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
Not applicable. May form combustible dust concentrations in air.
Product Code ALS5N0035
OTHER HAZARDS
Not applicable.
Page 2 / 8
AGHS – USA OSHA SDS
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.
Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet
Specific hazards arising from the chemical
Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Remove all sources of ignition. Do not breathe dust.
For emergency responders
Use personal protection recommended in Section 8.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be
created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for
disposal according to local regulations (see section 13).
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational
exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal
protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.
General Hygiene Considerations
Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Incompatible materials
Alcohols. Amines.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Product Code ALS5N0035
Page 3 / 8
AGHS – USA OSHA SDS
Control parameters
Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Carbon black
1333-86-4
TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
Titanium dioxide
13463-67-7
TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
Appropriate engineering controls
Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment. Do not breathe dust.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and
irritation of the skin at neck and wrists through contact with the powder are avoided.
Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Thermal Protection
No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state powder
Appearance No information available
Odor Odorless
Color brown
Odor Threshold No information available
pH value No information available
Melting point/freezing point No information available
Boiling point / boiling range No information available °C / °F
flash point 510 °C / 950 °F
evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor Pressure No information available
vapor density No information available
Density (lbs per US gallon) 10.28
Product Code ALS5N0035
Page 4 / 8
AGHS – USA OSHA SDS
specific gravity 1.23
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Alcohols. Amines.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact
Not applicable
Skin Contact
Not applicable
Ingestion
Not applicable
Inhalation
Not applicable
Numerical measures of toxicity – Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Carbon black
1333-86-4
– – –
Titanium dioxide
13463-67-7
> 10000 mg/kg ( Rat ) – –
Numerical measures of toxicity – Product Information
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity
According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints
since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon
black is thought to occur from use in paints since the pigment is bound to other materials.
Chemical Name ACGIH IARC NTP OSHA
Carbon black
1333-86-4
A3 Group 2B X
Product Code ALS5N0035
Page 5 / 8
AGHS – USA OSHA SDS
Titanium dioxide
13463-67-7
Group 2B X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 – Animal Carcinogen.
IARC (International Agency for Research on Cancer)
Group 2B – Possibly Carcinogenic to Humans.
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present.
Skin corrosion/irritation Not applicable
Serious eye damage/eye irritation Not applicable
Skin sensitization Not applicable
Respiratory sensitization Not applicable
Germ cell mutagenicity Not applicable
Carcinogenicity Not applicable
Reproductive Toxicity Not applicable
Specific target organ toxicity (single
exposure)
Not applicable
Specific target organ toxicity
(repeated exposure)
Not applicable
Aspiration hazard Not applicable
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Environmental precautions Prevent product from entering drains.
Persistence and degradability
No information available
Bioaccumulation
No information available
Mobility
No information available
Other adverse effects No information available
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.
Section 14: TRANSPORT INFORMATION
14.5 Environmental hazard Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
Section 15: REGULATORY INFORMATION
International Inventories
DOT IMDG IATA
14.1 UN/ID no Not regulated Not regulated Not regulated
14.2 Proper shipping name
14.3 Hazard Class
14.4 Packing Group
Product Code ALS5N0035
14.6 Special Provisions
Page 6 / 8
AGHS – USA OSHA SDS
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt
from listing
DSL – Canadian Domestic Substances List Not all components are listed or
exempt from listing
US Federal Regulations
SARA 311/312 Hazard Categories
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
US State Regulations
Rule 66 status of product
Not photochemically reactive.
U.S. EPA Label information
EPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Inert .
Carbon black
1333-86-4
.
Iron oxide (Fe2O3)
1309-37-1
.
Section 16: OTHER INFORMATION
HMIS
Health hazards 0
Flammability 1
Physical hazards 0
Personal Protection X
Supplier Address
Prepared By Product Stewardship
Product Code ALS5N0035
Revision date 25-Apr-2015
Page 7 / 8
Revision Note No information available
AGHS – USA OSHA SDS
Valspar Coatings
10300 Claude Freeman Dr.
Charlotte, NC 28262
704-548-2820
Valspar Powder Coatings
13129 Harland Dr. NE
Covington, GA 30014
770-784-4140
Disclaimer
The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national
legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and
control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS
should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS
SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND
DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.
End of Safety Data Sheet
Product Code ALS5N0035
Page 8 / 8
AGHS – USA OSHA SDS
**UnitIII_SDSSolvent.pdf**
This file is too large to display. [View in new window](https://www.sweetstudy.com/files/unitiii-sdssolvent-pdf-10180001)
**UnitIII_SDSSolvent.pdf**
This file is too large to display. [View in new window](https://www.sweetstudy.com/files/unitiii-sdssolvent-pdf-10180001)
**## OSH4302UnitIII_JHAforAssignment.docx**
You have been tasked with identifying health hazards associated with a production line at a manufacturing facility.
Employees at the beginning of the line use a solvent to clean the surface of medium-size auto parts, and then they place the parts on a moving line. As the parts move along the line, an employee sprays them with a powder coating, and the parts move through an oven. Another employee removes the parts from the line and places them in slots in a cart for transporting to shipping.
You have been provided
[safety data sheets for the solvent](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404059_1/xid-148404059_1) used for cleaning the parts and the
[powder coating](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404058_1/xid-148404058_1) that is used. Use the
[Basic Job Hazard Analysis form](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404057_1/xid-148404057_1) to identify the potential health hazards associated with the process. You will use the Basic Job Hazard Analysis form to enter your responses and to answer the four questions listed below.
Prepare a two-page homework assignment at the bottom of the JHA form summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
**Unit III BASIC JOB HAZARD ANALYSIS FORM**
**Directions:** List the steps involved in performing the process, and identify the potential hazards associated with each step.
| | |
| — | — |
| **Steps to Perform the Work Process** | **Hazards/Potential Hazards** |
| 1. | |
| 2. | |
| 3. | |
| 4. | |
| 5. | |
| 6. | |
Prepare a two-page homework assignment summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
1. What are the health hazards associated with the operation?
2. What are the primary exposure routes associated with each health hazard?
3. Are there any potential acute or chronic health effects for any of the health hazards you identified?
4. Are there any special hazards associated with any of the health hazards?
You may use the safety data sheets provided above, information from the OSHA or NIOSH websites, or academic references from the Internet to answer the questions. Citations are not required for this homework assignment; however you may want to use them in order to answer the questions.
**## UnitIII_SDSPaint.pdf**
SAFETY DATA SHEET
Revision date 25-Apr-2015 Version 2
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Code ALS5N0035
Product Name EARTH VEIN
Other means of identification
No information available
Recommended use of the chemical and restrictions on use
Paint, Coatings
Details of the supplier of the safety data sheet
See section 16 for more
information
The Valspar Corporation
PO Box 1461
Minneapolis, MN 55440
E-mail address msds@valspar.com
Emergency telephone number
United States of America 1-888-345-5732
American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924
Section 2: HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Product Code ALS5N0035
HAZARD STATEMENTS
Page 1 / 8
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
AGHS – USA OSHA SDS
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No weight-%
Carbon black 1333-86-4 1 – 3
Titanium dioxide 13463-67-7 0.1 – 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General advice
Get medical advice/attention if you feel unwell.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
PREVENTION
Do not handle until all safety precautions have been read and understood.
RESPONSE
Get medical advice/attention if you feel unwell.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
STORAGE
Store in a closed container.
DISPOSAL
Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
Not applicable. May form combustible dust concentrations in air.
Product Code ALS5N0035
OTHER HAZARDS
Not applicable.
Page 2 / 8
AGHS – USA OSHA SDS
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.
Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet
Specific hazards arising from the chemical
Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Remove all sources of ignition. Do not breathe dust.
For emergency responders
Use personal protection recommended in Section 8.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be
created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for
disposal according to local regulations (see section 13).
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational
exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal
protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.
General Hygiene Considerations
Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Incompatible materials
Alcohols. Amines.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Product Code ALS5N0035
Page 3 / 8
AGHS – USA OSHA SDS
Control parameters
Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Carbon black
1333-86-4
TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
Titanium dioxide
13463-67-7
TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
Appropriate engineering controls
Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment. Do not breathe dust.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and
irritation of the skin at neck and wrists through contact with the powder are avoided.
Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Thermal Protection
No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state powder
Appearance No information available
Odor Odorless
Color brown
Odor Threshold No information available
pH value No information available
Melting point/freezing point No information available
Boiling point / boiling range No information available °C / °F
flash point 510 °C / 950 °F
evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor Pressure No information available
vapor density No information available
Density (lbs per US gallon) 10.28
Product Code ALS5N0035
Page 4 / 8
AGHS – USA OSHA SDS
specific gravity 1.23
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Alcohols. Amines.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact
Not applicable
Skin Contact
Not applicable
Ingestion
Not applicable
Inhalation
Not applicable
Numerical measures of toxicity – Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Carbon black
1333-86-4
– – –
Titanium dioxide
13463-67-7
> 10000 mg/kg ( Rat ) – –
Numerical measures of toxicity – Product Information
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity
According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints
since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon
black is thought to occur from use in paints since the pigment is bound to other materials.
Chemical Name ACGIH IARC NTP OSHA
Carbon black
1333-86-4
A3 Group 2B X
Product Code ALS5N0035
Page 5 / 8
AGHS – USA OSHA SDS
Titanium dioxide
13463-67-7
Group 2B X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 – Animal Carcinogen.
IARC (International Agency for Research on Cancer)
Group 2B – Possibly Carcinogenic to Humans.
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present.
Skin corrosion/irritation Not applicable
Serious eye damage/eye irritation Not applicable
Skin sensitization Not applicable
Respiratory sensitization Not applicable
Germ cell mutagenicity Not applicable
Carcinogenicity Not applicable
Reproductive Toxicity Not applicable
Specific target organ toxicity (single
exposure)
Not applicable
Specific target organ toxicity
(repeated exposure)
Not applicable
Aspiration hazard Not applicable
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Environmental precautions Prevent product from entering drains.
Persistence and degradability
No information available
Bioaccumulation
No information available
Mobility
No information available
Other adverse effects No information available
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.
Section 14: TRANSPORT INFORMATION
14.5 Environmental hazard Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
Section 15: REGULATORY INFORMATION
International Inventories
DOT IMDG IATA
14.1 UN/ID no Not regulated Not regulated Not regulated
14.2 Proper shipping name
14.3 Hazard Class
14.4 Packing Group
Product Code ALS5N0035
14.6 Special Provisions
Page 6 / 8
AGHS – USA OSHA SDS
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt
from listing
DSL – Canadian Domestic Substances List Not all components are listed or
exempt from listing
US Federal Regulations
SARA 311/312 Hazard Categories
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
US State Regulations
Rule 66 status of product
Not photochemically reactive.
U.S. EPA Label information
EPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Inert .
Carbon black
1333-86-4
.
Iron oxide (Fe2O3)
1309-37-1
.
Section 16: OTHER INFORMATION
HMIS
Health hazards 0
Flammability 1
Physical hazards 0
Personal Protection X
Supplier Address
Prepared By Product Stewardship
Product Code ALS5N0035
Revision date 25-Apr-2015
Page 7 / 8
Revision Note No information available
AGHS – USA OSHA SDS
Valspar Coatings
10300 Claude Freeman Dr.
Charlotte, NC 28262
704-548-2820
Valspar Powder Coatings
13129 Harland Dr. NE
Covington, GA 30014
770-784-4140
Disclaimer
The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national
legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and
control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS
should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS
SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND
DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.
End of Safety Data Sheet
Product Code ALS5N0035
Page 8 / 8
AGHS – USA OSHA SDS
**UnitIII_SDSSolvent.pdf**
This file is too large to display. [View in new window](https://www.sweetstudy.com/files/unitiii-sdssolvent-pdf-10180001)
**## OSH4302UnitIII_JHAforAssignment.docx**
You have been tasked with identifying health hazards associated with a production line at a manufacturing facility.
Employees at the beginning of the line use a solvent to clean the surface of medium-size auto parts, and then they place the parts on a moving line. As the parts move along the line, an employee sprays them with a powder coating, and the parts move through an oven. Another employee removes the parts from the line and places them in slots in a cart for transporting to shipping.
You have been provided
[safety data sheets for the solvent](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404059_1/xid-148404059_1) used for cleaning the parts and the
[powder coating](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404058_1/xid-148404058_1) that is used. Use the
[Basic Job Hazard Analysis form](https://online.columbiasouthern.edu/bbcswebdav/pid-17153760-dt-asiobject-rid-148404057_1/xid-148404057_1) to identify the potential health hazards associated with the process. You will use the Basic Job Hazard Analysis form to enter your responses and to answer the four questions listed below.
Prepare a two-page homework assignment at the bottom of the JHA form summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
**Unit III BASIC JOB HAZARD ANALYSIS FORM**
**Directions:** List the steps involved in performing the process, and identify the potential hazards associated with each step.
| | |
| — | — |
| **Steps to Perform the Work Process** | **Hazards/Potential Hazards** |
| 1. | |
| 2. | |
| 3. | |
| 4. | |
| 5. | |
| 6. | |
Prepare a two-page homework assignment summarizing your health hazard analysis and answer these questions from the Basic Job Hazard Analysis form.
1. What are the health hazards associated with the operation?
2. What are the primary exposure routes associated with each health hazard?
3. Are there any potential acute or chronic health effects for any of the health hazards you identified?
4. Are there any special hazards associated with any of the health hazards?
You may use the safety data sheets provided above, information from the OSHA or NIOSH websites, or academic references from the Internet to answer the questions. Citations are not required for this homework assignment; however you may want to use them in order to answer the questions.
**## UnitIII_SDSPaint.pdf**
SAFETY DATA SHEET
Revision date 25-Apr-2015 Version 2
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Code ALS5N0035
Product Name EARTH VEIN
Other means of identification
No information available
Recommended use of the chemical and restrictions on use
Paint, Coatings
Details of the supplier of the safety data sheet
See section 16 for more
information
The Valspar Corporation
PO Box 1461
Minneapolis, MN 55440
E-mail address msds@valspar.com
Emergency telephone number
United States of America 1-888-345-5732
American Samoa, Guam, Northern Mariana Islands, Puerto Rico, U.S. Virgin Islands 1-800-255-3924
Section 2: HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Product Code ALS5N0035
HAZARD STATEMENTS
Page 1 / 8
Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)
AGHS – USA OSHA SDS
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No weight-%
Carbon black 1333-86-4 1 – 3
Titanium dioxide 13463-67-7 0.1 – 0.3
*The exact percentage (concentration) of composition has been withheld as a trade secret.
Section 4: FIRST AID MEASURES
First Aid Measures
General advice
Get medical advice/attention if you feel unwell.
Eye contact
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed
PREVENTION
Do not handle until all safety precautions have been read and understood.
RESPONSE
Get medical advice/attention if you feel unwell.
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/attention.
Skin
Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.
Inhalation
IF INHALED: Call a POISON CENTER or doctor if you feel unwell.
Ingestion
Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
STORAGE
Store in a closed container.
DISPOSAL
Dispose of contents/containers in accordance with local regulations.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC)
Not applicable. May form combustible dust concentrations in air.
Product Code ALS5N0035
OTHER HAZARDS
Not applicable.
Page 2 / 8
AGHS – USA OSHA SDS
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Note to physicians Treat symptomatically.
Section 5: FIRE FIGHTING MEASURES
Suitable extinguishing media
Water spray (fog). Carbon dioxide (CO2). Alcohol resistant foam.
Not to be used for safety reasons: Inert gas under high pressure (e.g. CO2), water jet
Specific hazards arising from the chemical
Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe
fumes.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is
out. Do not allow run-off from fire-fighting to enter drains or water courses.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Remove all sources of ignition. Do not breathe dust.
For emergency responders
Use personal protection recommended in Section 8.
Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations.
Methods and material for containment and cleaning up
Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Dispose of waste product or used containers according to local regulations. Do not use a dry brush as dust clouds or static can be
created. Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for
disposal according to local regulations (see section 13).
Section 7: HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Precautions should be taken to prevent the formation of dusts in concentrations above flammable, explosive or occupational
exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal
protection recommended in Section 8. Comply with the health and safety at work laws. Prevent product from entering drains.
General Hygiene Considerations
Take off all contaminated clothing and wash it before reuse. Wash hands thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers
that have been opened must be carefully resealed and kept upright to prevent leakage.
Incompatible materials
Alcohols. Amines.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Product Code ALS5N0035
Page 3 / 8
AGHS – USA OSHA SDS
Control parameters
Exposure Limits
If S* appears in the OEL table, it indicates this chemical contains a skin notation.
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Carbon black
1333-86-4
TWA: 3 mg/m3 inhalable fraction TWA: 3.5 mg/m3 IDLH: 1750 mg/m3
TWA: 3.5 mg/m3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
Titanium dioxide
13463-67-7
TWA: 10 mg/m3 TWA: 15 mg/m3 total dust IDLH: 5000 mg/m3
Appropriate engineering controls
Engineering Controls
Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear
suitable respiratory equipment. Do not breathe dust.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin and body protection
Wear suitable protective clothing. Care should be taken in the selection of protective clothing to ensure that inflammation and
irritation of the skin at neck and wrists through contact with the powder are avoided.
Hand Protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of
chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on
breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance
or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Thermal Protection
No information available
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state powder
Appearance No information available
Odor Odorless
Color brown
Odor Threshold No information available
pH value No information available
Melting point/freezing point No information available
Boiling point / boiling range No information available °C / °F
flash point 510 °C / 950 °F
evaporation rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor Pressure No information available
vapor density No information available
Density (lbs per US gallon) 10.28
Product Code ALS5N0035
Page 4 / 8
AGHS – USA OSHA SDS
specific gravity 1.23
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Other information
Section 10: STABILITY AND REACTIVITY
Reactivity No information available.
Chemical stability Stable under normal conditions.
Possibility of Hazardous Reactions None under normal processing.
Hazardous polymerization None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Alcohols. Amines.
Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Aldehydes.
Section 11: TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Eye contact
Not applicable
Skin Contact
Not applicable
Ingestion
Not applicable
Inhalation
Not applicable
Numerical measures of toxicity – Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Carbon black
1333-86-4
– – –
Titanium dioxide
13463-67-7
> 10000 mg/kg ( Rat ) – –
Numerical measures of toxicity – Product Information
UNKNOWN ACUTE TOXICITY 0% of the mixture consists of ingredient(s) of unknown toxicity.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity
According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints
since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon
black is thought to occur from use in paints since the pigment is bound to other materials.
Chemical Name ACGIH IARC NTP OSHA
Carbon black
1333-86-4
A3 Group 2B X
Product Code ALS5N0035
Page 5 / 8
AGHS – USA OSHA SDS
Titanium dioxide
13463-67-7
Group 2B X
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 – Animal Carcinogen.
IARC (International Agency for Research on Cancer)
Group 2B – Possibly Carcinogenic to Humans.
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present.
Skin corrosion/irritation Not applicable
Serious eye damage/eye irritation Not applicable
Skin sensitization Not applicable
Respiratory sensitization Not applicable
Germ cell mutagenicity Not applicable
Carcinogenicity Not applicable
Reproductive Toxicity Not applicable
Specific target organ toxicity (single
exposure)
Not applicable
Specific target organ toxicity
(repeated exposure)
Not applicable
Aspiration hazard Not applicable
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity
Environmental precautions Prevent product from entering drains.
Persistence and degradability
No information available
Bioaccumulation
No information available
Mobility
No information available
Other adverse effects No information available
Section 13: DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated packaging Improper disposal or reuse of this container may be dangerous and illegal. Empty
containers must be scrapped or reconditioned.
Section 14: TRANSPORT INFORMATION
14.5 Environmental hazard Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No information available
Section 15: REGULATORY INFORMATION
International Inventories
DOT IMDG IATA
14.1 UN/ID no Not regulated Not regulated Not regulated
14.2 Proper shipping name
14.3 Hazard Class
14.4 Packing Group
Product Code ALS5N0035
14.6 Special Provisions
Page 6 / 8
AGHS – USA OSHA SDS
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory All components are listed or exempt
from listing
DSL – Canadian Domestic Substances List Not all components are listed or
exempt from listing
US Federal Regulations
SARA 311/312 Hazard Categories
Acute health hazard No
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No
US State Regulations
Rule 66 status of product
Not photochemically reactive.
U.S. EPA Label information
EPA Pesticide registration number Not applicable
U.S. State Right-to-Know Regulations
Chemical Name .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Non-Hazardous Ingredient – Proprietary CAS .
Proprietary Inert .
Carbon black
1333-86-4
.
Iron oxide (Fe2O3)
1309-37-1
.
Section 16: OTHER INFORMATION
HMIS
Health hazards 0
Flammability 1
Physical hazards 0
Personal Protection X
Supplier Address
Prepared By Product Stewardship
Product Code ALS5N0035
Revision date 25-Apr-2015
Page 7 / 8
Revision Note No information available
AGHS – USA OSHA SDS
Valspar Coatings
10300 Claude Freeman Dr.
Charlotte, NC 28262
704-548-2820
Valspar Powder Coatings
13129 Harland Dr. NE
Covington, GA 30014
770-784-4140
Disclaimer
The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national
legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and
control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS
should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS
SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND
DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL,
INCIDENTAL OR CONSEQUENTIAL DAMAGES.
End of Safety Data Sheet
Product Code ALS5N0035
Page 8 / 8
AGHS – USA OSHA SDS
**UnitIII_SDSSolvent.pdf**
This file is too large to display. [View in new window](https://www.sweetstudy.com/files/unitiii-sdssolvent-pdf-10180001)
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